CMD30 FisMat2023 - Submission - View

Abstract title: Applications in energy and environment of nanocolumnar films
Submitting author: José Miguel García-Martín
Affiliation: CSIC
Affiliation Address: Instituto de Micro y Nanotecnología, IMN-CSIC, Tres Cantos (Madrid), Spain.
Country: Spain
Other authors and affiliations: María Ujué González (1), Grégory Barbillon (2), Elena Navarro (3), Fernando Fresno (4), Christophe Humbert (5), Fanny Béron (6), Felipe Tejo (7), Lidia Martínez (8), Yves Huttel (8), Juan Escrig (7), Víctor A. de la Peña O'Shea (4). (1) Instituto de Micro y Nanotecnología, IMN-CSIC, Tres Cantos (Madrid), Spain. (2) EPF-Ecole d’Ingénieurs, Cachan, France. (3) Dep. de Física de Materiales, Universidad Complutense de Madrid, Madrid, Spain. (4) Photoactivated Processes Unit, IMDEA Energy, Móstoles (Madrid), Spain. (5) Institut de Chimie Physique, Université Paris-Saclay, Orsay, France. (6) Instituto de Física Gleb Wataghin, Universidade Estadual de Campinas (UNICAMP), Campinas, Brazil. (7) Departamento de Física, Universidad de Santiago de Chile (USACH), Santiago, Chile. (8) Instituto de Ciencia de Materiales de Madrid, ICMM-CSIC, Madrid, Spain.
Abstract
Glancing Angle Deposition (GLAD) with magnetron sputtering (MS) is an easy and versatile route to fabricate nanocolumnar films in large areas (several cm2 and above) in a single-step process, in clear contrast to other techniques in the nanoscale range such as e-beam lithography and ion-beam lithography. The morphology of the nanocolumns can be controlled depending on several parameters such as the gas pressure, the angle of inclination of the substrate and its possible rotation, the electromagnetic power, the deposition time, and the optional use of collimating masks [1-4]. Moreover, as GLAD with MS it is usually carried out at RT and does not involve chemical products (thus, without associated recycling issues), this technique is environmentally friendly. In this talk, I will start explaining the fundamentals of GLAD with MS and then I will present some recent examples of nanocolumnar films that are of interest in the field of energy and environment: Gold nanocolumnar templates for effective chemical sensing by surface-enhanced Raman scattering [5], Iron nanocolumnar films with tailored magnetic behavior [6], and Titanium oxide nanocolumnar films that exhibit photo‐induced self‐cleaning properties [7]. It will be finally shown that this latter effect can be enhanced when the nanocolumns are decorated with gold nanoparticles using a gas aggregation source that is also based on MS. References:[1] R. Alvarez et al., Nanotechnology 24, 045604 (2013). [2] R. Alvarez et al., J. Phys. D: Appl. Phys. 49, 045303 (2016). [3] A. Vitrey et al., Beilstein J. Nanotechnol. 8, 434 (2017).[4] G. Troncoso et al., Appl. Surf. Sci. 526, 146699 (2020).[5] G. Barbillon et al., Nanomaterials 12, 4157 (2022).[6] E. Navarro et al., Nanomaterials 12, 1186 (2022).[7] F. Fresno et al., Adv. Sustainable Syst. 5, 2100071 (2021).