FisMat2017 - Submission - View

Abstract's title: Non-monotonic knotting probability and knot length of semiflexible rings: the competing roles of entropy and bending energy
Submitting author: Lucia Coronel
Affiliation: SISSA International School for Advanced Studies
Affiliation Address: via Bonomea, 265 - 34136 Trieste ITALY
Country: Italy
Oral presentation/Poster (Author's request): Poster
Other authors and affiliations: Enzo Orlandini ( Dipartimento di Fisica e Astronomia ‘‘Galileo Galilei’’, sezione CNISM, Universita` degli Studi di Padova), Cristian Micheletti (SISSA, International School for Advanced Studies)

We consider self-avoiding rings of up to 1000 beads and study, by Monte Carlo techniques, how their equilibrium knotting properties depend on the bending rigidity. When the rings are taken from the rigid to fully-flexible limit, their average compactness increases, as expected. However, this progressive compactification is not parallelled by a steady increase of the abundance of knots. In fact the knotting probability, Pk, has a prominent maximum when the persistence length is a few times larger than the bead size. At similar bending rigidities, the knot length has, instead, a minimum. We show that the observed non-monotonicity of Pk arises from the competition between two effects. The first one is the entropic cost of introducing a knot. The second one is the gain in bending energy due to the presence of essential crossings. These, in fact, constrain the knotted region and keep it less bent than average. The two competing effects make knots maximally abundant when the persistence length is 5–10 times larger than the bead size. At such intermediate bending rigidities, knots in the chains of 500 and 1000 beads are 40 times more likely than in the fully-flexible limit.